Formation, characterisation and exploitation of covalently bonded porphyrin nanostructures
Pi-conjugated molecules such as porphyrins and fullerenes with tunable electronic properties are appealing building blocks for the construction of functional materials with novel electronic, chemical and photophysical properties. This proposal explores the formation of molecular nanomeshes on solid surfaces using functionalized porphyrins as the basic building blocks. The nanomesh structures are formed through ‘bottom-up’ two-dimensional molecular assembly mediated by either hydrogen or covalent bonding. These nanomeshes will be used to host fullerene molecules thus forming donor-acceptor complexes with applications in novel photovoltaic and sensor devices. These structures will be characterised using scanning probe microscopies, photoelectron spectroscopy and synchrotron based techniques.
Tony Cafolla, Mary Pryce
Dr. Alexi Preobrajenski, Lund University Sweden
Prof Mathias Senge, Trinity College Dublin
Prof. Iggy McGovern, Trinity College Dublin
Science Foundation Ireland